Please use this identifier to cite or link to this item: http://hdl.handle.net/10316/8177
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dc.contributor.authorCoelho, Jorge F. J.-
dc.contributor.authorCarvalho, Erica Y.-
dc.contributor.authorMarques, Dina S.-
dc.contributor.authorPopov, Anatoliy V.-
dc.contributor.authorGoncalves, Pedro M.-
dc.contributor.authorGil, Maria H.-
dc.date.accessioned2009-02-09T12:16:13Z-
dc.date.available2009-02-09T12:16:13Z-
dc.date.issued2007en_US
dc.identifier.citationMacromolecular Chemistry and Physics. 208:11 (2007) 1218-1227en_US
dc.identifier.urihttp://hdl.handle.net/10316/8177-
dc.description.abstractLiving radical polymerization of lauryl acrylate was achieved by SET/DTLRP in water catalyzed by sodium dithionite. The work describes the synthesis of a highly hydrophobic and polar monomer in aqueous medium. The plots of versus conversion and ln[M]0/[M] versus time are linear, indicating a controlled polymerization. This method leads to alpha,omega-diiodopoly(lauryl acrylate)s that can be further functionalized. The MWDs were determined using a combination of three detectors: RALLS, DV, and RI. The method studied in this work represents a possible route to prepare well-tailored macromolecules made of LA in environment friendly reaction medium. The syndiotactic content is 75%.en_US
dc.language.isoengeng
dc.rightsopenAccesseng
dc.titleSynthesis of Poly(lauryl acrylate) by Single-Electron Transfer/Degenerative Chain Transfer Living Radical Polymerization Catalyzed by Na2S2O4 in Wateren_US
dc.typearticleen_US
dc.identifier.doi10.1002/macp.200700015en_US
item.fulltextCom Texto completo-
item.grantfulltextopen-
item.languageiso639-1en-
Appears in Collections:FCTUC Eng.Química - Artigos em Revistas Internacionais
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