Please use this identifier to cite or link to this item:
Title: Synthesis of Poly(lauryl acrylate) by Single-Electron Transfer/Degenerative Chain Transfer Living Radical Polymerization Catalyzed by Na2S2O4 in Water
Authors: Coelho, Jorge F. J. 
Carvalho, Erica Y. 
Marques, Dina S. 
Popov, Anatoliy V. 
Goncalves, Pedro M. 
Gil, Maria H. 
Issue Date: 2007
Citation: Macromolecular Chemistry and Physics. 208:11 (2007) 1218-1227
Abstract: Living radical polymerization of lauryl acrylate was achieved by SET/DTLRP in water catalyzed by sodium dithionite. The work describes the synthesis of a highly hydrophobic and polar monomer in aqueous medium. The plots of versus conversion and ln[M]0/[M] versus time are linear, indicating a controlled polymerization. This method leads to alpha,omega-diiodopoly(lauryl acrylate)s that can be further functionalized. The MWDs were determined using a combination of three detectors: RALLS, DV, and RI. The method studied in this work represents a possible route to prepare well-tailored macromolecules made of LA in environment friendly reaction medium. The syndiotactic content is 75%.
DOI: 10.1002/macp.200700015
Rights: openAccess
Appears in Collections:FCTUC Eng.Química - Artigos em Revistas Internacionais

Files in This Item:
File Description SizeFormat
obra.pdf220.41 kBAdobe PDFView/Open
Show full item record


checked on Feb 18, 2020

Page view(s)

checked on Aug 12, 2020


checked on Aug 12, 2020

Google ScholarTM




Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.