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https://hdl.handle.net/10316/5861
Title: | Allylic and benzylic oxidation reactions with sodium chlorite | Authors: | Silvestre, Samuel M. Salvador, Jorge A. R. |
Keywords: | Sodium chlorite; Allylic oxidation; Benzylic oxidation; Transition-metal free | Issue Date: | 2007 | Citation: | Tetrahedron. 63:11 (2007) 2439-2445 | Abstract: | Various allylic and benzylic substrates were selectively oxidized to the corresponding enones in good yields using sodium chlorite, either in combination with tert-butyl hydroperoxide in stoichiometric conditions, or associated with N-hydroxyphthalimide as catalyst. These oxidation reactions were effectively and economically performed under mild, transition-metal free conditions and therefore the dual challenge of cost effectiveness and benign nature of the processes was met with. | URI: | https://hdl.handle.net/10316/5861 | DOI: | 10.1016/j.tet.2007.01.012 | Rights: | openAccess |
Appears in Collections: | FFUC- Artigos em Revistas Internacionais |
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