Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/105415
Title: | Exploring Electrochemically Mediated ATRP of Styrene | Authors: | De Bon, Francesco Carlan, Gian Marco Tognella, Enrico Isse, Abdirisak Ahmed |
Keywords: | styrene; eATRP; temporal control; copper catalyst | Issue Date: | 2021 | Publisher: | MDPI | Serial title, monograph or event: | Processes | Volume: | 9 | Issue: | 8 | Abstract: | Electrochemically mediated atom transfer radical polymerization (eATRP) of styrene was studied in detail by using CuBr2/TPMA (TPMA = tris(2-pyridylmethyl)amine) as a catalyst. Redox properties of various Cu(II) species were investigated in CH3CN, dimethylformamide (DMF), and dimethyl sulfoxide (DMSO) both in the absence and presence of 50% (v/v) styrene. This investigation together with preliminary eATRP experiments at 80 C indicated DMF as the best solvent. The effects of catalyst, monomer, and initiator concentrations were also examined. The livingness of the polymerization was studied by chain extension and electrochemical temporal control of polymerization. | URI: | https://hdl.handle.net/10316/105415 | ISSN: | 2227-9717 | DOI: | 10.3390/pr9081327 | Rights: | openAccess |
Appears in Collections: | I&D CEMMPRE - Artigos em Revistas Internacionais |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
Exploring-electrochemically-mediated-ATRP-of-styreneProcesses.pdf | 2.88 MB | Adobe PDF | View/Open |
SCOPUSTM
Citations
4
checked on Oct 7, 2024
WEB OF SCIENCETM
Citations
5
checked on Oct 2, 2024
Page view(s)
52
checked on Oct 15, 2024
Download(s)
26
checked on Oct 15, 2024
Google ScholarTM
Check
Altmetric
Altmetric
This item is licensed under a Creative Commons License