Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/5271
Title: | Synthesis of 2-halo-2H-azirines from phosphorus ylides | Authors: | Melo, Teresa M. V. D. Pinho e Gonsalves, António M. d'A. Rocha Lopes, Cláudia S. J. Gilchrist, Thomas L. |
Issue Date: | 1999 | Citation: | Tetrahedron Letters. 40:4 (1999) 789-792 | Abstract: | [alpha]-Oxophosphonium ylides (3a-3e) react with N-chlorosuccinimide and N-bromosuccinimide in the presence of azidotrimethylsilane giving the corresponding haloazidoalkenes (4a-4g) with elimination of triphenylphosphine oxide. These compounds were completely converted to the 2H-azirines 5a-5g on heating in heptane. | URI: | https://hdl.handle.net/10316/5271 | DOI: | 10.1002/chin.199915131 | Rights: | openAccess |
Appears in Collections: | FCTUC Química - Artigos em Revistas Internacionais |
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