Please use this identifier to cite or link to this item: http://hdl.handle.net/10316/5222
Title: On the mechanism of carboxylic acid co-catalyst assisted metalloporphyrin oxidations
Authors: d'A. Rocha Gonsalves, António M. 
Serra, Arménio C. 
Keywords: Metalloporphyrin; Catalysis; Hydrogen peroxide; Oxidation
Issue Date: 2001
Keywords: Metalloporphyrin; Catalysis; Hydrogen peroxide; Oxidation
Issue Date: 2001
Citation: Journal of Molecular Catalysis A: Chemical. 168:1-2 (2001) 25-32
Abstract: The role of the carboxylic acid as co-catalyst in metalloporphyrin catalytic hydrogen peroxide oxidations is discussed, taking into account its dependence on the ratio relatively to the catalyst. The catalytic efficiency and stability of the catalyst in the presence of an excess of carboxylic acid suggests that a metallo-acylperoxo complex can be the effective oxidation intermediate.
URI: http://hdl.handle.net/10316/5222
Rights: openAccess
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais

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