Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/5222
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Gonsalves, António M. d'A. Rocha | - |
dc.contributor.author | Serra, Arménio C. | - |
dc.date.accessioned | 2008-09-01T15:06:02Z | - |
dc.date.available | 2008-09-01T15:06:02Z | - |
dc.date.issued | 2001 | en_US |
dc.identifier.citation | Journal of Molecular Catalysis A: Chemical. 168:1-2 (2001) 25-32 | en_US |
dc.identifier.uri | https://hdl.handle.net/10316/5222 | - |
dc.description.abstract | The role of the carboxylic acid as co-catalyst in metalloporphyrin catalytic hydrogen peroxide oxidations is discussed, taking into account its dependence on the ratio relatively to the catalyst. The catalytic efficiency and stability of the catalyst in the presence of an excess of carboxylic acid suggests that a metallo-acylperoxo complex can be the effective oxidation intermediate. | en_US |
dc.description.uri | http://www.sciencedirect.com/science/article/B6TGM-42G6XGY-4/1/0ef5cfc94471f6985d77385ef339282b | en_US |
dc.format.mimetype | aplication/PDF | en |
dc.language.iso | eng | eng |
dc.rights | openAccess | eng |
dc.subject | Metalloporphyrin | en_US |
dc.subject | Catalysis | en_US |
dc.subject | Hydrogen peroxide | en_US |
dc.subject | Oxidation | en_US |
dc.title | On the mechanism of carboxylic acid co-catalyst assisted metalloporphyrin oxidations | en_US |
dc.type | article | en_US |
dc.identifier.doi | 10.1016/S1381-1169(00)00490-8 | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.openairetype | article | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
item.fulltext | Com Texto completo | - |
item.languageiso639-1 | en | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.researchunit | CEMMPRE - Centre for Mechanical Engineering, Materials and Processes | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.orcid | 0000-0001-9987-7301 | - |
crisitem.author.orcid | 0000-0001-8664-2757 | - |
Appears in Collections: | FCTUC Química - Artigos em Revistas Internacionais |
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file07102e698d6c48c68ee084582c7eeaf2.pdf | 278.74 kB | Adobe PDF | View/Open |
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