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Title: Reactivity of a-Oxophosphonium Ylides: A Contribution to the Mechanistics
Authors: Melo, Teresa M. Pinho e 
Gonsalves, António M. d'A. Rocha 
Carrapato, Sara M. 
Taborda, Ana M. 
Keywords: Phosphorus ylides; Tetrasubstituted alkenes
Issue Date: 1999
Publisher: Molecular Diversity Preservation International
Citation: Molecules. 4:7 (1999) 219-231
Serial title, monograph or event: Molecules
Issue: 4:7
Abstract: Ylides 1f and 1g react with chlorine, with bromine and with N-chlorosuccinimide in the presence of a range of nucleophiles. The 2,3-disubstitutedbutenedioates obtained in this way allow us to gather more information about the mechanism involved. Ylide 1c was also studied showing similar reactivity and leading to the highly selective synthesis of 2,3- disubstituted-3-phenylpropenoates
ISSN: 1420-3049
Rights: openAccess
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais

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