Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/13017| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Melo, Teresa M. Pinho e | - |
| dc.contributor.author | Gonsalves, António M. d'A. Rocha | - |
| dc.contributor.author | Carrapato, Sara M. | - |
| dc.contributor.author | Taborda, Ana M. | - |
| dc.date.accessioned | 2010-04-19T13:56:12Z | - |
| dc.date.available | 2010-04-19T13:56:12Z | - |
| dc.date.issued | 1999 | - |
| dc.identifier.citation | Molecules. 4:7 (1999) 219-231 | en_US |
| dc.identifier.issn | 1420-3049 | - |
| dc.identifier.uri | https://hdl.handle.net/10316/13017 | - |
| dc.description.abstract | Ylides 1f and 1g react with chlorine, with bromine and with N-chlorosuccinimide in the presence of a range of nucleophiles. The 2,3-disubstitutedbutenedioates obtained in this way allow us to gather more information about the mechanism involved. Ylide 1c was also studied showing similar reactivity and leading to the highly selective synthesis of 2,3- disubstituted-3-phenylpropenoates | en_US |
| dc.language.iso | eng | en_US |
| dc.publisher | Molecular Diversity Preservation International | en_US |
| dc.rights | openAccess | en_US |
| dc.subject | Phosphorus ylides | en_US |
| dc.subject | Tetrasubstituted alkenes | en_US |
| dc.title | Reactivity of a-Oxophosphonium Ylides: A Contribution to the Mechanistics | en_US |
| dc.type | article | en_US |
| degois.publication.firstPage | 219 | en_US |
| degois.publication.lastPage | 231 | en_US |
| degois.publication.issue | 4:7 | en_US |
| degois.publication.title | Molecules | en_US |
| dc.identifier.doi | 10.3390/40700219 | - |
| uc.controloAutoridade | Sim | - |
| item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
| item.openairetype | article | - |
| item.cerifentitytype | Publications | - |
| item.grantfulltext | open | - |
| item.fulltext | Com Texto completo | - |
| item.languageiso639-1 | en | - |
| crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
| crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
| crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
| crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
| crisitem.author.orcid | 0000-0003-3256-4954 | - |
| crisitem.author.orcid | 0000-0001-9987-7301 | - |
| Appears in Collections: | FCTUC Química - Artigos em Revistas Internacionais | |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Reactivity of a-Oxophosphonium Ylides.pdf | 48.02 kB | Adobe PDF | View/Open |
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