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Title: Experimental and Theoretical Studies on the Structure and Photoluminescent Properties of New Mononuclear and Homodinuclear Europium(III)β-Diketonate Complexes
Authors: Martins, João P. 
Martín-Ramos, Pablo 
Chamorro-Posada, Pedro
Silva, Pedro S. Pereira 
Martín-Gil, Jesús
Hernández-Navarro, Salvador
Silva, Manuela Ramos 
Issue Date: 2015
Publisher: Hindawi
Project: Santander Universidades through “Becas Iberoamérica Jóvenes Profesores e Investigadores, España 2015” scholarship program 
Serial title, monograph or event: Advances in Condensed Matter Physics
Volume: 2015
Abstract: Two novel europium(III) complexes, a monomer and a homodimer, with 1-(4-chlorophenyl)-4,4,4-trifluoro-1,3-butanedione (Hcbtfa) and 5-chloro-1,10-phenanthroline (cphen) ligands, formulated as [Eu(cbtfa)3(cphen)] and [Eu2(cbtfa)4(cphen)2(CH3O)2], have been synthesized. Their structures have been elucidated by X-ray diffraction and their absorption and emission properties have been studied in the solid state. The experimental data has then been used to test the recently released LUMPAC software, a promising tool which can facilitate the design ofmore efficient lanthanide light-conversion molecular devices by combining ground state geometry, excited state energy, and luminescent properties calculations.
ISSN: 1687-8108
DOI: 10.1155/2015/205047
Rights: openAccess
Appears in Collections:FCTUC Física - Artigos em Revistas Internacionais
I&D CFis - Artigos em Revistas Internacionais

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