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https://hdl.handle.net/10316/10620| Title: | Rotational Isomerism in Acetic Acid: The First Experimental Observation of the High-Energy Conformer | Authors: | Maçôas, Ermelinda M. S. Khriachtchev, Leonid Pettersson, Mika Fausto, Rui Räsänen, Markku |
Issue Date: | 31-Dec-2003 | Publisher: | American Chemical Society | Citation: | Journal of the American Chemical Society. 125:52 (2003) 16188-16189 | Abstract: | The high-energy conformer of acetic acid (cis-AA) is produced in an Ar matrix by vibrational excitation of the OH stretching overtone of the ground conformational state (trans-AA). IR-absorption spectroscopy provides a clear identification of the reaction product. cis-AA converts back to trans-AA in a time scale of minutes at 8 K by tunneling. | URI: | https://hdl.handle.net/10316/10620 | ISSN: | 0002-7863 | DOI: | 10.1021/ja038341a | Rights: | openAccess |
| Appears in Collections: | FCTUC Química - Artigos em Revistas Internacionais |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| Rotational Isomerism in Acetic Acid The First Experimental Observation.pdf | 42.7 kB | Adobe PDF | View/Open |
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