Please use this identifier to cite or link to this item: https://hdl.handle.net/10316/10620
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dc.contributor.authorMaçôas, Ermelinda M. S.-
dc.contributor.authorKhriachtchev, Leonid-
dc.contributor.authorPettersson, Mika-
dc.contributor.authorFausto, Rui-
dc.contributor.authorRäsänen, Markku-
dc.date.accessioned2009-07-10T09:59:35Z-
dc.date.available2009-07-10T09:59:35Z-
dc.date.issued2003-12-31-
dc.identifier.citationJournal of the American Chemical Society. 125:52 (2003) 16188-16189en_US
dc.identifier.issn0002-7863-
dc.identifier.urihttps://hdl.handle.net/10316/10620-
dc.description.abstractThe high-energy conformer of acetic acid (cis-AA) is produced in an Ar matrix by vibrational excitation of the OH stretching overtone of the ground conformational state (trans-AA). IR-absorption spectroscopy provides a clear identification of the reaction product. cis-AA converts back to trans-AA in a time scale of minutes at 8 K by tunneling.en_US
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsopenAccesseng
dc.titleRotational Isomerism in Acetic Acid: The First Experimental Observation of the High-Energy Conformeren_US
dc.typearticleen_US
dc.identifier.doi10.1021/ja038341a-
uc.controloAutoridadeSim-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypearticle-
item.cerifentitytypePublications-
item.grantfulltextopen-
item.fulltextCom Texto completo-
item.languageiso639-1en-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.orcid0000-0002-8264-6854-
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais
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