Utilize este identificador para referenciar este registo:
https://hdl.handle.net/10316/103395
Título: | Diels-Alder Cycloaddition Reactions in Sustainable Media | Autor: | Soares, Maria I. L. Cardoso, Ana L. Melo, Teresa M. V. D. Pinho e |
Palavras-chave: | Diels–Alder reaction; green solvent; bio-based solvent; deep eutectic solvents; water | Data: | 15-Fev-2022 | Projeto: | UIDB/00313/2020 UIDP/00313/2020 |
Título da revista, periódico, livro ou evento: | Molecules | Volume: | 27 | Número: | 4 | Resumo: | Diels-Alder cycloaddition reaction is one of the most powerful strategies for the construction of six-membered carbocyclic and heterocyclic systems, in most cases with high regio- and stereoselectivity. In this review, an insight into the most relevant advances on sustainable Diels-Alder reactions since 2010 is provided. Various environmentally benign solvent systems are discussed, namely bio-based derived solvents (such as glycerol and gluconic acid), polyethylene glycol, deep eutectic solvents, supercritical carbon dioxide, water and water-based aqueous systems. Issues such as method's scope, efficiency, selectivity and reaction mechanism, as well as sustainability, advantages and limitations of these reaction media, are addressed. | URI: | https://hdl.handle.net/10316/103395 | ISSN: | 1420-3049 | DOI: | 10.3390/molecules27041304 | Direitos: | openAccess |
Aparece nas coleções: | FCTUC Química - Artigos em Revistas Internacionais |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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DielsAlder-Cycloaddition-Reactions-in-Sustainable-MediaMolecules.pdf | 12.92 MB | Adobe PDF | Ver/Abrir |
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