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Title: Diels-Alder Cycloaddition Reactions in Sustainable Media
Authors: Soares, Maria I. L. 
Cardoso, Ana L. 
Melo, Teresa M. V. D. Pinho e 
Keywords: Diels–Alder reaction; green solvent; bio-based solvent; deep eutectic solvents; water
Issue Date: 15-Feb-2022
Project: UIDB/00313/2020 
Serial title, monograph or event: Molecules
Volume: 27
Issue: 4
Abstract: Diels-Alder cycloaddition reaction is one of the most powerful strategies for the construction of six-membered carbocyclic and heterocyclic systems, in most cases with high regio- and stereoselectivity. In this review, an insight into the most relevant advances on sustainable Diels-Alder reactions since 2010 is provided. Various environmentally benign solvent systems are discussed, namely bio-based derived solvents (such as glycerol and gluconic acid), polyethylene glycol, deep eutectic solvents, supercritical carbon dioxide, water and water-based aqueous systems. Issues such as method's scope, efficiency, selectivity and reaction mechanism, as well as sustainability, advantages and limitations of these reaction media, are addressed.
ISSN: 1420-3049
DOI: 10.3390/molecules27041304
Rights: openAccess
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais

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