Please use this identifier to cite or link to this item: https://hdl.handle.net/10316/5223
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dc.contributor.authorGonsalves, António Manuel d'Albuquerque Rocha-
dc.contributor.authorSerra, Maria Elisa da Silva-
dc.contributor.authorSilva, Manuela Ramos-
dc.contributor.authorBeja, Ana Matos-
dc.contributor.authorPaixão, José António-
dc.contributor.authorVeiga, Luiz Alte da-
dc.date.accessioned2008-09-01T15:06:03Z-
dc.date.available2008-09-01T15:06:03Z-
dc.date.issued2001en_US
dc.identifier.citationJournal of Molecular Catalysis A: Chemical. 168:1-2 (2001) 53-59en_US
dc.identifier.urihttps://hdl.handle.net/10316/5223-
dc.description.abstractThe N-aryl pyrrolidine diphosphine (R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine was obtained from natural tartaric acid. Contrary to our preliminary expectations, this new chiral ligand proved to be less selective than the corresponding N-benzyl pyrrolidine diphosphine. An attempted explanation of the observed behaviour based on the stereochemistry of the ligand as shown by X-ray crystallography is presented.en_US
dc.description.urihttp://www.sciencedirect.com/science/article/B6TGM-42G6XGY-8/1/25fa9c4e0f48edebc992db1e0b302bf0en_US
dc.format.mimetypeaplication/PDFen
dc.language.isoengeng
dc.rightsopenAccesseng
dc.subjectTransfer hydrogenationen_US
dc.subjectPyrrolidine diphosphineen_US
dc.subjectAsymmetric catalysisen_US
dc.subjectFive-membered chelateen_US
dc.subjectRhodiumen_US
dc.title(R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine: an N-aryl pyrrolidine ligand for enantioselective transfer hydrogenationen_US
dc.typearticleen_US
dc.identifier.doi10.1016/S1381-1169(00)00531-8-
uc.controloAutoridadeSim-
item.fulltextCom Texto completo-
item.grantfulltextopen-
item.languageiso639-1en-
item.cerifentitytypePublications-
item.openairetypearticle-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.researchunitCFisUC – Center for Physics of the University of Coimbra-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.orcid0000-0001-9987-7301-
crisitem.author.orcid0000-0002-4562-7072-
crisitem.author.orcid0000-0001-9555-8856-
crisitem.author.orcid0000-0003-1449-5123-
crisitem.author.orcid0000-0003-4634-7395-
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais
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