Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/5223
DC Field | Value | Language |
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dc.contributor.author | Gonsalves, António Manuel d'Albuquerque Rocha | - |
dc.contributor.author | Serra, Maria Elisa da Silva | - |
dc.contributor.author | Silva, Manuela Ramos | - |
dc.contributor.author | Beja, Ana Matos | - |
dc.contributor.author | Paixão, José António | - |
dc.contributor.author | Veiga, Luiz Alte da | - |
dc.date.accessioned | 2008-09-01T15:06:03Z | - |
dc.date.available | 2008-09-01T15:06:03Z | - |
dc.date.issued | 2001 | en_US |
dc.identifier.citation | Journal of Molecular Catalysis A: Chemical. 168:1-2 (2001) 53-59 | en_US |
dc.identifier.uri | https://hdl.handle.net/10316/5223 | - |
dc.description.abstract | The N-aryl pyrrolidine diphosphine (R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine was obtained from natural tartaric acid. Contrary to our preliminary expectations, this new chiral ligand proved to be less selective than the corresponding N-benzyl pyrrolidine diphosphine. An attempted explanation of the observed behaviour based on the stereochemistry of the ligand as shown by X-ray crystallography is presented. | en_US |
dc.description.uri | http://www.sciencedirect.com/science/article/B6TGM-42G6XGY-8/1/25fa9c4e0f48edebc992db1e0b302bf0 | en_US |
dc.format.mimetype | aplication/PDF | en |
dc.language.iso | eng | eng |
dc.rights | openAccess | eng |
dc.subject | Transfer hydrogenation | en_US |
dc.subject | Pyrrolidine diphosphine | en_US |
dc.subject | Asymmetric catalysis | en_US |
dc.subject | Five-membered chelate | en_US |
dc.subject | Rhodium | en_US |
dc.title | (R,R)-N-phenyl-3,4-bis(diphenylphosphino)pyrrolidine: an N-aryl pyrrolidine ligand for enantioselective transfer hydrogenation | en_US |
dc.type | article | en_US |
dc.identifier.doi | 10.1016/S1381-1169(00)00531-8 | - |
uc.controloAutoridade | Sim | - |
item.fulltext | Com Texto completo | - |
item.grantfulltext | open | - |
item.languageiso639-1 | en | - |
item.cerifentitytype | Publications | - |
item.openairetype | article | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.researchunit | CFisUC – Center for Physics of the University of Coimbra | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.orcid | 0000-0001-9987-7301 | - |
crisitem.author.orcid | 0000-0002-4562-7072 | - |
crisitem.author.orcid | 0000-0001-9555-8856 | - |
crisitem.author.orcid | 0000-0003-1449-5123 | - |
crisitem.author.orcid | 0000-0003-4634-7395 | - |
Appears in Collections: | FCTUC Química - Artigos em Revistas Internacionais |
Files in This Item:
File | Description | Size | Format | |
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file9802c5297dc44a9c91cc1767d69fd75c.pdf | 123.7 kB | Adobe PDF | View/Open |
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