Please use this identifier to cite or link to this item: http://hdl.handle.net/10316/5167
DC FieldValueLanguage
dc.contributor.authorPinho e Melo, Teresa M. V. D.-
dc.contributor.authorCardoso, Ana L.-
dc.contributor.authorRocha Gonsalves, António M. dA.-
dc.date.accessioned2008-09-01T15:05:06Z-
dc.date.available2008-09-01T15:05:06Z-
dc.date.issued2003en_US
dc.identifier.citationTetrahedron. 59:13 (2003) 2345-2351en_US
dc.identifier.urihttp://hdl.handle.net/10316/5167-
dc.description.abstractThe dehalogenation of 2-halo-3-phenyl-2H-azirine-2-carboxylates is described. Using sodium borohydride and tributyltin hydride 3-phenyl-2H-azirine-2-carboxylates were obtained in moderate yields. The synthesis of a new 2-bromo-2H-azirines with a chiral auxiliary, 10-phenylsulfonylisobornyl 2-bromo-3-phenyl-2H-azirine-2-carboxylate, is reported. Its dehalogenation led to 10-phenylsulfonylisobornyl 2H-azirine-2-carboxylate as single stereoisomer together with the formation of 10-phenylsulfonylisobornyl acetate.en_US
dc.description.urihttp://www.sciencedirect.com/science/article/B6THR-482NK06-7/1/b576da25bb07c16918052295f89735c8en_US
dc.format.mimetypeaplication/PDFen
dc.language.isoengeng
dc.rightsopenAccesseng
dc.subjectdehalogenationen_US
dc.subject2-halo-2H-azirine-2-carboxylatesen_US
dc.subjectchiral 2H-azirine-2-carboxylatesen_US
dc.titleReactivity of 2-halo-2H-azirines. Part 3: Dehalogenation of 2-halo-2H-azirine-2-carboxylatesen_US
dc.typearticleen_US
uc.controloAutoridadeSim-
item.fulltextCom Texto completo-
item.languageiso639-1en-
item.grantfulltextopen-
crisitem.author.deptFaculdade de Farmácia, Universidade de Coimbra-
crisitem.author.deptFaculdade de Ciências e Tecnologia, Universidade de Coimbra-
crisitem.author.deptFaculdade de Ciências e Tecnologia, Universidade de Coimbra-
crisitem.author.parentdeptUniversidade de Coimbra-
crisitem.author.parentdeptUniversidade de Coimbra-
crisitem.author.researchunitCoimbra Chemistry Center-
crisitem.author.researchunitCoimbra Chemistry Center-
crisitem.author.researchunitCoimbra Chemistry Center-
crisitem.author.orcid0000-0003-3256-4954-
crisitem.author.orcid0000-0003-0551-7255-
crisitem.author.orcid0000-0001-9987-7301-
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais
Files in This Item:
File Description SizeFormat
filee9c8c10110634be39cb654ce8aa3388c.pdf265.6 kBAdobe PDFView/Open
Show simple item record

Page view(s) 50

323
checked on Jun 30, 2020

Download(s)

103
checked on Jun 30, 2020

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.