Please use this identifier to cite or link to this item: https://hdl.handle.net/10316/114025
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dc.contributor.authorde Souza, Vitória Barbosa-
dc.contributor.authorda Rocha, Vinícius N-
dc.contributor.authorPiquini, Paulo Cesar-
dc.contributor.authorChaves, Otávio Augusto-
dc.contributor.authorIglesias, Bernardo A-
dc.date.accessioned2024-03-15T10:38:49Z-
dc.date.available2024-03-15T10:38:49Z-
dc.date.issued2023-02-01-
dc.identifier.issn1420-3049pt
dc.identifier.urihttps://hdl.handle.net/10316/114025-
dc.description.abstractThe trans-A2B-corrole series was prepared starting with 5-(pentafluorophenyl)dipyrromethene, which was then reacted with respective aryl-substituted aldehyde by Gryko synthesis. It was further characterized by HRMS and electrochemical methods. In addition, we investigated experimental photophysical properties (absorption, emission by steady-state and time-resolved fluorescence) in several solvents and TDDFT calculations, aggregation, photostability and reactive oxygen species generation (ROS), which are relevant when selecting photosensitizers used in photodynamic therapy and many other photo-applications. In addition, we also evaluated the biomolecule-binding properties with CT-DNA and HSA by spectroscopy, viscometry and molecular docking calculations assays.pt
dc.language.isoengpt
dc.publisherMDPIpt
dc.relationUIDB/00313/2020pt
dc.relationCNPq (Universal—403210/2021-6 and PQ—305458/2021-3), CAPES (Finance code 001) and FAPERGS grants (PQ Gaucho—21/2551-0002114-4). P.C. Piquini also to thanks CNPq (312388/2018-7), CAPES and FAPERGS.pt
dc.rightsopenAccesspt
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt
dc.subjectcorrolespt
dc.subjecttrans-A2B-corrolespt
dc.subjectphotophysicspt
dc.subjectphotobiologypt
dc.subject.meshMolecular Docking Simulationpt
dc.subject.meshPhotobiologypt
dc.subject.meshPorphyrinspt
dc.subject.meshPhotochemotherapypt
dc.titleEffects of Substituents on the Photophysical/Photobiological Properties of Mono-Substituted Corrolespt
dc.typearticle-
degois.publication.firstPage1385pt
degois.publication.issue3pt
degois.publication.titleMoleculespt
dc.peerreviewedyespt
dc.identifier.doi10.3390/molecules28031385pt
degois.publication.volume28pt
dc.date.embargo2023-02-01*
uc.date.periodoEmbargo0pt
item.openairetypearticle-
item.fulltextCom Texto completo-
item.languageiso639-1en-
item.grantfulltextopen-
item.cerifentitytypePublications-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
crisitem.project.grantnoCoimbra Chemistry Center-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.orcid0000-0001-6211-7659-
Appears in Collections:I&D CQC - Artigos em Revistas Internacionais
FCTUC Química - Artigos em Revistas Internacionais
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