Please use this identifier to cite or link to this item: https://hdl.handle.net/10316/110172
DC FieldValueLanguage
dc.contributor.authorSerra, M. Elisa Silva-
dc.contributor.authorMurtinho, Dina M. B.-
dc.contributor.authorGoth, Albertino João Brito-
dc.date.accessioned2023-11-16T09:48:14Z-
dc.date.available2023-11-16T09:48:14Z-
dc.date.issued2009-
dc.identifier.issn1551-7012pt
dc.identifier.urihttps://hdl.handle.net/10316/110172-
dc.description.abstractThe in situ formed Ti(IV) complexes of several pyrrolidine-based chiral salen ligands derived from natural (L)-tartaric acid were evaluated as catalysts in the enantioselective trimethylsilylcyanation of benzaldehyde. The catalysts were found to be very active, producing the corresponding product, O-trimethylsilylmandelonitrile, in high yields (>94%) and enantioselectivities of up to 88%.pt
dc.language.isoengpt
dc.publisherArkat USApt
dc.relationChymiotechnonpt
dc.relationREEQ/481/QUI/2006pt
dc.rightsopenAccesspt
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt
dc.subjectSalenspt
dc.subjecttartaric acidpt
dc.subjectpyrrolidinept
dc.subjectenantioselectivept
dc.subjecttrimethylsilylcyanationpt
dc.subjectbenzaldehydept
dc.titleEnantioselective trimethylsilylcyanation of benzaldehyde using pyrrolidine-based chiral salen ligandspt
dc.typearticle-
degois.publication.firstPage64pt
degois.publication.lastPage69pt
degois.publication.issue5pt
degois.publication.titleArkivocpt
dc.peerreviewedyespt
dc.identifier.doi10.3998/ark.5550190.0011.507pt
degois.publication.volume2010pt
dc.date.embargo2009-01-01*
uc.date.periodoEmbargo0pt
item.fulltextCom Texto completo-
item.grantfulltextopen-
item.languageiso639-1en-
item.cerifentitytypePublications-
item.openairetypearticle-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.orcid0000-0002-4562-7072-
crisitem.author.orcid0000-0002-1391-9855-
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais
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