Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/110151
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yuste, Consuelo | - |
dc.contributor.author | Silva, Manuela Ramos | - |
dc.contributor.author | Ghadermazi, Mohammad | - |
dc.contributor.author | Feizi, Fariba | - |
dc.contributor.author | Motieiyan, Elham | - |
dc.date.accessioned | 2023-11-15T11:13:25Z | - |
dc.date.available | 2023-11-15T11:13:25Z | - |
dc.date.issued | 2010-11-24 | - |
dc.identifier.issn | 1600-5368 | pt |
dc.identifier.uri | https://hdl.handle.net/10316/110151 | - |
dc.description.abstract | The asymmetric unit of the title compound, (C(6)H(9)N(2))[Co(C(7)H(3)NO(4))(C(7)H(4)NO(4))]·C(7)H(5)NO(4)·3H(2)O, contains one (6-carb-oxy-pyridine-2-carboxyl-ato)(pyridine-2,6-dicarboxyl-ato)cobaltate(II) anion, one phenyl-hydrazinium cation, one pyridine-2,6-dicarb-oxy-lic acid mol-ecule and three uncoordin-ated water mol-ecules, part of which are disordered. The Co(II) ion is coordinated by a pyridine-2,6-dicarboxyl-ate ion and a 6-carb-oxy-pyridine-2-carboxyl-ate ligand almost perpendicular to each other [the angle between the least-squares planes is 87.38 (4)°] and is surrounded by two O atoms and two N atoms in the equatorial plane and two O atoms in axial positions, resulting in a distorted octa-hedral coordination geometry. There is an extensive three-dimensional network of O-H⋯O and N-H⋯O hydrogen bonds, which link the components. | pt |
dc.language.iso | eng | pt |
dc.publisher | International Union of Crystallography | pt |
dc.relation | PTDC/FIS/102284/2008 | pt |
dc.rights | openAccess | pt |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | pt |
dc.subject | single-crystal X-ray study | pt |
dc.subject | T = 293 K; mean (C–C) = 0.005 A° | pt |
dc.subject | Hatom completeness 93% | pt |
dc.subject | disorder in solvent or counterion | pt |
dc.subject | R factor = 0.043 | pt |
dc.subject | wR factor = 0.167 | pt |
dc.subject | data-to-parameter ratio = 12.0 | pt |
dc.title | Phenyl-hydrazinium (6-carb-oxy-pyridine-2-carboxyl-ato)(pyridine-2,6-dicarboxyl-ato)cobaltate(II)-pyridine-2,6-dicarb-oxy-lic acid-water (1/1/3) | pt |
dc.type | article | - |
degois.publication.firstPage | m1643 | pt |
degois.publication.lastPage | m1644 | pt |
degois.publication.issue | Pt 12 | pt |
degois.publication.title | Acta Crystallographica Section E: Structure Reports Online | pt |
dc.peerreviewed | yes | pt |
dc.identifier.doi | 10.1107/S1600536810048191 | pt |
degois.publication.volume | 66 | pt |
dc.date.embargo | 2010-11-24 | * |
uc.date.periodoEmbargo | 0 | pt |
item.grantfulltext | open | - |
item.cerifentitytype | Publications | - |
item.languageiso639-1 | en | - |
item.openairetype | article | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | Com Texto completo | - |
crisitem.author.orcid | 0000-0001-9555-8856 | - |
Appears in Collections: | FCTUC Física - Artigos em Revistas Internacionais |
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This item is licensed under a Creative Commons License