Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/109826
DC Field | Value | Language |
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dc.contributor.author | Adib, Marwa | - |
dc.contributor.author | El Glaoui, Meher | - |
dc.contributor.author | Silva, Pedro Sidónio Pereira da | - |
dc.contributor.author | Silva, Manuela Ramos | - |
dc.contributor.author | Ben Nasr, Cherif | - |
dc.date.accessioned | 2023-10-30T12:13:56Z | - |
dc.date.available | 2023-10-30T12:13:56Z | - |
dc.date.issued | 2012-02-01 | - |
dc.identifier.issn | 1600-5368 | pt |
dc.identifier.uri | https://hdl.handle.net/10316/109826 | - |
dc.description.abstract | In the title compound, {(C(5)H(14)N(2))[Cd(2)Cl(6)]·H(2)O}(n), the asymmetric unit contains one piperazinediium cation, one [Cd(2)Cl(6)](2-) anion and a water mol-ecule. The coordination geometries of the two Cd(2+) cations are distorted octa-hedral. Adjacent Cd(II) atoms are inter-connected alternately by paired chloride bridges, generating polymeric chains parallel to [010]. Neighbouring chains are connected by O-H⋯Cl hydrogen bonds involving the water mol-ecules, forming layers at z = n/2. The crystal packing is further stabilized by inter-molecular N-H⋯Cl and N-H⋯O hydrogen bonds, one of which is bifurcated. | pt |
dc.language.iso | eng | pt |
dc.publisher | International Union of Crystallography | pt |
dc.relation | SFRH/BD/38387/2008 | pt |
dc.rights | openAccess | pt |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | pt |
dc.subject | single-crystal X-ray study | pt |
dc.subject | T = 293 K | pt |
dc.subject | mean (C–C) = 0.003 A° | pt |
dc.subject | R factor = 0.018 | pt |
dc.subject | wR factor = 0.045 | pt |
dc.subject | data-to-parameter ratio = 23.9 | pt |
dc.title | Poly[piperazine-1,4-diium [μ(4)-chlorido-μ(3)-chlorido-tri-μ(2)-chlorido-chloridodicadmate(II)] monohydrate] | pt |
dc.type | article | - |
degois.publication.firstPage | m175 | pt |
degois.publication.lastPage | m175 | pt |
degois.publication.issue | Pt 2 | pt |
degois.publication.title | Acta Crystallographica Section E: Structure Reports Online | pt |
dc.peerreviewed | yes | pt |
dc.identifier.doi | 10.1107/S1600536812001626 | pt |
degois.publication.volume | 68 | pt |
dc.date.embargo | 2012-02-01 | * |
uc.date.periodoEmbargo | 0 | pt |
item.grantfulltext | open | - |
item.cerifentitytype | Publications | - |
item.languageiso639-1 | en | - |
item.openairetype | article | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | Com Texto completo | - |
crisitem.author.researchunit | CFisUC – Center for Physics of the University of Coimbra | - |
crisitem.author.orcid | 0000-0002-6760-4517 | - |
crisitem.author.orcid | 0000-0001-9555-8856 | - |
Appears in Collections: | FCTUC Física - Artigos em Revistas Internacionais |
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File | Description | Size | Format | |
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Polypiperazine14diium--sub4subchlorido-sub3sub-chloridotri-sub2subchloridochloridodicadmateII-monohydrateActa-Crystallographica-Section-E-Structure-Reports-Online.pdf | 590.12 kB | Adobe PDF | View/Open |
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