Utilize este identificador para referenciar este registo:
https://hdl.handle.net/10316/109342
Campo DC | Valor | Idioma |
---|---|---|
dc.contributor.author | Carrilho, Rui M. B. | - |
dc.contributor.author | Pereira, Mariette M. | - |
dc.contributor.author | Maria, Teresa M. R. | - |
dc.contributor.author | Eusébio, M. Ermelinda | - |
dc.contributor.author | Paiva, V. H. | - |
dc.date.accessioned | 2023-10-10T12:22:50Z | - |
dc.date.available | 2023-10-10T12:22:50Z | - |
dc.date.issued | 2014-10-01 | - |
dc.identifier.issn | 1600-5368 | pt |
dc.identifier.uri | https://hdl.handle.net/10316/109342 | - |
dc.description.abstract | In the title compound, C28H19F3O4S, a new 2'-benz-yloxy (R)-BINOL derivative containing a tri-fluoro-methane-sulfonate group in the 2-position, the planes of the two naphthyl ring systems (r.m.s. deviations = 0.012 and 0.019 Å) are at an angle of 73.36 (2)°, and the planes of the benzyl ring and the naphthyl ring system bound to the ether O atom are at an angle of 75.67 (4)°. In the crystal, mol-ecules are linked via C-H⋯F hydrogen bonds, forming chains propagating along [100]. The chains are linked via a weak C-F⋯π inter-action and weak π-π inter-actions [shortest inter-centroid distance = 3.9158 (12) Å], forming a three-dimensional structure. The absolute structure of the mol-ecule in the crystal was determined by resonant scattering [Flack parameter = 0.02 (6)]. | pt |
dc.language.iso | eng | pt |
dc.publisher | International Union of Crystallography | pt |
dc.relation | PEst-C/FIS/UI0036/2011 | pt |
dc.rights | openAccess | pt |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | pt |
dc.subject | crystal structure; (R)-BINOL | pt |
dc.subject | binaphthyl | pt |
dc.subject | sulfonate | pt |
dc.subject | chiral | pt |
dc.title | Crystal structure of (R)-2'-benz-yloxy-[1,1'-binaphthalen]-2-yl tri-fluoro-methane-sulfonate | pt |
dc.type | article | - |
degois.publication.firstPage | o1096 | pt |
degois.publication.lastPage | o1097 | pt |
degois.publication.issue | Pt 10 | pt |
degois.publication.title | Acta Crystallographica Section E: Structure Reports Online | pt |
dc.peerreviewed | yes | pt |
dc.identifier.doi | 10.1107/S1600536814019096 | pt |
degois.publication.volume | 70 | pt |
dc.date.embargo | 2014-10-01 | * |
uc.date.periodoEmbargo | 0 | pt |
item.languageiso639-1 | en | - |
item.grantfulltext | open | - |
item.fulltext | Com Texto completo | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.openairetype | article | - |
item.cerifentitytype | Publications | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.researchunit | MARE - Marine and Environmental Sciences Centre | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.orcid | 0000-0001-9923-359X | - |
crisitem.author.orcid | 0000-0003-4958-7677 | - |
crisitem.author.orcid | 0000-0002-7143-2228 | - |
crisitem.author.orcid | 0000-0002-5515-7721 | - |
crisitem.author.orcid | 0000-0001-6368-9579 | - |
Aparece nas coleções: | FCTUC Física - Artigos em Revistas Internacionais FCTUC Química - Artigos em Revistas Internacionais |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
---|---|---|---|---|
Crystal-structure-of-R2benzyloxy11binaphthalen2yl-trifluoromethanesulfonateActa-Crystallographica-Section-E-Structure-Reports-Online.pdf | 419.72 kB | Adobe PDF | Ver/Abrir |
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