Please use this identifier to cite or link to this item: https://hdl.handle.net/10316/10623
DC FieldValueLanguage
dc.contributor.authorPettersson, Mika-
dc.contributor.authorMaçôas, Ermelinda M. S.-
dc.contributor.authorKhriachtchev, Leonid-
dc.contributor.authorFausto, Rui-
dc.contributor.authorRäsänen, Markku-
dc.date.accessioned2009-07-10T10:25:03Z-
dc.date.available2009-07-10T10:25:03Z-
dc.date.issued2003-04-09-
dc.identifier.citationJournal of the American Chemical Society. 125:14 (2003) 4058-4059en_US
dc.identifier.issn0002-7863-
dc.identifier.urihttps://hdl.handle.net/10316/10623-
dc.description.abstractPhotoinduced conformational isomerization of formic acid has been studied in a low-temperature argon matrix. It is found that conformational isomerization occurs when the photon energy is below the energy barrier for this process. The quantum yield for the process near the top of the barrier is comparable with the quantum yield above the barrier and drops at lower energies. The isomerization takes place via a tunneling mechanism.en_US
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsopenAccesseng
dc.titleConformational Isomerization of Formic Acid by Vibrational Excitation at Energies below the Torsional Barrieren_US
dc.typearticleen_US
dc.identifier.doi10.1021/ja0295016-
uc.controloAutoridadeSim-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypearticle-
item.cerifentitytypePublications-
item.grantfulltextopen-
item.fulltextCom Texto completo-
item.languageiso639-1en-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.orcid0000-0002-8264-6854-
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais
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