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https://hdl.handle.net/10316/10380
Title: | Exploring the Photocatalytic Properties and the Long-Lifetime Chemosensor Ability of Cl2[Ru(Bpy)2L] (L = 2,5,8,11,14-Pentaaza[15])-2,2‘-bipyridilophane) | Authors: | Lodeiro, Carlos Pina, Fernando Parola, A. Jorge Bencini, Andrea Bianchi, Antonio Bazzicalupi, Carla Ciattini, Samuele Giorgi, Claudia Masotti, Andrea Valtancoli, Barbara Melo, J. Seixas de |
Issue Date: | 17-Dec-2001 | Publisher: | American Chemical Society | Citation: | Inorganic Chemistry. 40:26 (2001) 6813-6819 | Abstract: | In this work a new water-soluble long-lifetime chemosensor, containing a polyamine unit connected to a complexed Ru(II) metal center, is described. Its crystal structure has been characterized by X-ray analysis. The polyamine macrocyclic unit is capable of anchoring cationic or anionic substrates, according to its protonation state. Examples of electron transfer involving the ruthenium complex core and the bound substrate are presented. The photocatalytic ability of such a system is illustrated by the oxidation of iodide to iodine promoted by light absorption at 436 nm. | URI: | https://hdl.handle.net/10316/10380 | ISSN: | 0020-1669 | DOI: | 10.1021/ic0105213 | Rights: | openAccess |
Appears in Collections: | FCTUC Química - Artigos em Revistas Internacionais |
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Exploring the Photocatalytic Properties.pdf | 121.39 kB | Adobe PDF | View/Open |
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