Please use this identifier to cite or link to this item: http://hdl.handle.net/10316/10380
Title: Exploring the Photocatalytic Properties and the Long-Lifetime Chemosensor Ability of Cl2[Ru(Bpy)2L] (L = 2,5,8,11,14-Pentaaza[15])-2,2‘-bipyridilophane)
Authors: Lodeiro, Carlos 
Pina, Fernando 
Parola, A. Jorge 
Bencini, Andrea 
Bianchi, Antonio 
Bazzicalupi, Carla 
Ciattini, Samuele 
Giorgi, Claudia 
Masotti, Andrea 
Valtancoli, Barbara 
Melo, J. Seixas de 
Issue Date: 17-Dec-2001
Publisher: American Chemical Society
Citation: Inorganic Chemistry. 40:26 (2001) 6813-6819
Abstract: In this work a new water-soluble long-lifetime chemosensor, containing a polyamine unit connected to a complexed Ru(II) metal center, is described. Its crystal structure has been characterized by X-ray analysis. The polyamine macrocyclic unit is capable of anchoring cationic or anionic substrates, according to its protonation state. Examples of electron transfer involving the ruthenium complex core and the bound substrate are presented. The photocatalytic ability of such a system is illustrated by the oxidation of iodide to iodine promoted by light absorption at 436 nm.
URI: http://hdl.handle.net/10316/10380
ISSN: 0020-1669
DOI: 10.1021/ic0105213
Rights: openAccess
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais

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