Please use this identifier to cite or link to this item: https://hdl.handle.net/10316/100822
DC FieldValueLanguage
dc.contributor.authorPiñeiro, Marta-
dc.contributor.authorGomes, Carla-
dc.contributor.authorPeixoto, Mariana-
dc.date.accessioned2022-07-13T10:13:40Z-
dc.date.available2022-07-13T10:13:40Z-
dc.date.issued2021-
dc.identifier.issn1751-8253pt
dc.identifier.issn1751-7192pt
dc.identifier.urihttps://hdl.handle.net/10316/100822-
dc.description.abstractThe synthesis of chlorins was performed by hydrogenation of porphyrins using diimide generated and consumed under mechanical activation. The reaction conditions achievable under ball milling, absence of solvent and use of hydrazine hydrate as diimide source, allowed the hydrogenation of porphyrins with high conversion, high selectivity, and nearly ideal sustainability scores (atom economy of 97% and E-factor of 0.96).pt
dc.language.isoengpt
dc.relationFCT grant number PD/BD/135531/2018pt
dc.relationUIDB/00313/2020pt
dc.relationUIDP/00313/2020pt
dc.rightsopenAccesspt
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/pt
dc.subjectchlorinpt
dc.subjecthydrazine hydratept
dc.subjectMechanochemistrypt
dc.subjectporphyrinpt
dc.subjectreductionpt
dc.titleMechanochemical in situ generated gas reactant for the solvent-free hydrogenation of porphyrinspt
dc.typearticle-
degois.publication.firstPage339pt
degois.publication.lastPage344pt
degois.publication.issue2pt
degois.publication.titleGreen Chemistry Letters and Reviewspt
dc.peerreviewedyespt
dc.identifier.doi10.1080/17518253.2021.1921283pt
degois.publication.volume14pt
dc.date.embargo2021-01-01*
uc.date.periodoEmbargo0pt
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypearticle-
item.cerifentitytypePublications-
item.grantfulltextopen-
item.fulltextCom Texto completo-
item.languageiso639-1en-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.researchunitCQC - Coimbra Chemistry Centre-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.parentresearchunitFaculty of Sciences and Technology-
crisitem.author.orcid0000-0002-7460-3758-
crisitem.author.orcid0000-0003-2540-7029-
Appears in Collections:I&D CQC - Artigos em Revistas Internacionais
FCTUC Química - Artigos em Revistas Internacionais
Files in This Item:
File Description SizeFormat
Mechanochemical-in-situ-generated-gas-reactant-for-the-solventfree-hydrogenation-of-porphyrinsGreen-Chemistry-Letters-and-Reviews.pdf1.41 MBAdobe PDFView/Open
Show simple item record

SCOPUSTM   
Citations

2
checked on Nov 17, 2022

WEB OF SCIENCETM
Citations

1
checked on Nov 15, 2022

Page view(s)

76
checked on Apr 17, 2024

Download(s)

41
checked on Apr 17, 2024

Google ScholarTM

Check

Altmetric

Altmetric


This item is licensed under a Creative Commons License Creative Commons