Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/99947
DC Field | Value | Language |
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dc.contributor.author | Nogueira, Bernardo Albuquerque | - |
dc.contributor.author | Ogruc Ildiz, Gulce | - |
dc.contributor.author | Henriques, Marta S. C. | - |
dc.contributor.author | Paixão, José António de Carvalho | - |
dc.contributor.author | Fausto, Rui | - |
dc.date.accessioned | 2022-04-26T09:37:03Z | - |
dc.date.available | 2022-04-26T09:37:03Z | - |
dc.date.issued | 2017-07-13 | - |
dc.identifier.issn | 0022-2860 | pt |
dc.identifier.uri | https://hdl.handle.net/10316/99947 | - |
dc.description.abstract | In a previous study [Nogueira, B. A.; Ildiz, G. O.; Canotilho, J.; Eus ebio, M. E. S.; Fausto, R. J. Phys. Chem. A, 2014, 118, 5994e6008], two different polymorphs of 1-methylhydantoin (1-MH, C4H6N2O2) were identified using infrared spectroscopy, differential scanning calorimetry and polarized-light thermal microscopy. Unfortunately, at that time it was not possible to structurally characterize in detail the second polymorph (polymorph II) of the compound, due to lack of suitable crystals for X-ray diffraction structure determination. In this article, a throughout investigation of the polymorphism of 1-MH is presented. Screening for polymorphs was performed by recrystallization from different solvents, and the structure of polymorph II was determined for the first time by single crystal X-ray diffraction. The spectroscopic characterization of this polymorph was also undertaken, by Raman spectroscopy, which was also used to follow the phase transition between the two polymorphs (the well-known polymorph I, and the newly described polymorph II), showing that even though their structures are significantly distinct, the transition is a non-destructive one. | pt |
dc.language.iso | eng | pt |
dc.publisher | Elsevier | pt |
dc.rights | openAccess | pt |
dc.subject | 1-Methylhydantoin | pt |
dc.subject | Polymorphism | pt |
dc.subject | Raman spectroscopy | pt |
dc.subject | X-ray diffraction | pt |
dc.title | Structural and spectroscopic characterization of the second polymorph of 1-methylhydantoin | pt |
dc.type | article | - |
degois.publication.firstPage | 111 | pt |
degois.publication.lastPage | 118 | pt |
degois.publication.issue | 1148 | pt |
degois.publication.title | Journal of Molecular Structure | pt |
dc.peerreviewed | yes | pt |
dc.identifier.doi | 10.1016/j.molstruc.2017.07.028 | pt |
dc.date.embargo | 2017-07-13 | * |
uc.date.periodoEmbargo | 0 | pt |
item.fulltext | Com Texto completo | - |
item.grantfulltext | open | - |
item.languageiso639-1 | en | - |
item.cerifentitytype | Publications | - |
item.openairetype | article | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
crisitem.author.researchunit | Faculty of Sciences and Technology | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.researchunit | CFisUC – Center for Physics of the University of Coimbra | - |
crisitem.author.researchunit | CQC - Coimbra Chemistry Centre | - |
crisitem.author.parentresearchunit | University of Coimbra | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.orcid | 0000-0002-1756-377X | - |
crisitem.author.orcid | 0000-0002-7827-5050 | - |
crisitem.author.orcid | 0000-0003-4634-7395 | - |
crisitem.author.orcid | 0000-0002-8264-6854 | - |
Appears in Collections: | I&D CQC - Artigos em Revistas Internacionais |
Files in This Item:
File | Description | Size | Format | |
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Structural and spectroscopic characterization of the second polymorph of 1-Methylhydantoin.pdf | 1.68 MB | Adobe PDF | View/Open |
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