Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/8280
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ribeiro-Claro, Paulo J. A. | - |
dc.contributor.author | Costa, António M. Amorim da | - |
dc.contributor.author | Vueba, Manuel L. | - |
dc.contributor.author | Pina, M. Eugénia | - |
dc.contributor.author | Amado, Ana M. | - |
dc.date.accessioned | 2009-02-09T14:31:46Z | - |
dc.date.available | 2009-02-09T14:31:46Z | - |
dc.date.issued | 2006 | en_US |
dc.identifier.citation | Journal of Raman Spectroscopy. 37:4 (2006) 472-479 | en_US |
dc.identifier.uri | https://hdl.handle.net/10316/8280 | - |
dc.description.abstract | The inclusion complexes of 4-X-benzaldehyde guests (X = F, Cl, Br) in alpha-, beta-and gamma-cyclodextrins (alphaCD, betaCD and gammaCD) were prepared and characterized by means of thermogravimetry, differential scanning calorimetry (DSC) and vibrational spectroscopy. The stoichiometry of the inclusion complexes ranges from 2:1 to 1:2, depending on the cavity size of the host. Sensitive vibrational modes such as C-O and ring CH stretching modes were used to monitor the effects of the inclusion process and to assess the preferred inclusion geometry for each host-guest pair. On the whole, the spectral observations suggest that the small alphaCD cavity imposes important structural restrictions on the guest molecule, while the larger gammaCD cavity allows lsquoliquid-typersquo intermolecular contacts. Copyright © 2005 John Wiley & Sons, Ltd. | en_US |
dc.language.iso | eng | eng |
dc.rights | openAccess | eng |
dc.title | Para-halogenated benzaldehyde molecules included in cyclodextrins: a combined spectroscopic and thermal analysis | en_US |
dc.type | article | en_US |
dc.identifier.doi | 10.1002/jrs.1419 | en_US |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.openairetype | article | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
item.fulltext | Com Texto completo | - |
item.languageiso639-1 | en | - |
crisitem.author.researchunit | CIEPQPF – Chemical Process Engineering and Forest Products Research Centre | - |
crisitem.author.researchunit | QFM-UC – Molecular Physical-Chemistry R&D Unit | - |
crisitem.author.parentresearchunit | Faculty of Sciences and Technology | - |
crisitem.author.orcid | 0000-0001-8554-7192 | - |
crisitem.author.orcid | 0000-0003-0189-1370 | - |
Appears in Collections: | FCTUC Química - Artigos em Revistas Internacionais |
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