Please use this identifier to cite or link to this item: http://hdl.handle.net/10316/8177
Title: Synthesis of Poly(lauryl acrylate) by Single-Electron Transfer/Degenerative Chain Transfer Living Radical Polymerization Catalyzed by Na2S2O4 in Water
Authors: Coelho, Jorge F. J. 
Carvalho, Erica Y. 
Marques, Dina S. 
Popov, Anatoliy V. 
Goncalves, Pedro M. 
Gil, Maria H. 
Issue Date: 2007
Citation: Macromolecular Chemistry and Physics. 208:11 (2007) 1218-1227
Abstract: Living radical polymerization of lauryl acrylate was achieved by SET/DTLRP in water catalyzed by sodium dithionite. The work describes the synthesis of a highly hydrophobic and polar monomer in aqueous medium. The plots of versus conversion and ln[M]0/[M] versus time are linear, indicating a controlled polymerization. This method leads to alpha,omega-diiodopoly(lauryl acrylate)s that can be further functionalized. The MWDs were determined using a combination of three detectors: RALLS, DV, and RI. The method studied in this work represents a possible route to prepare well-tailored macromolecules made of LA in environment friendly reaction medium. The syndiotactic content is 75%.
URI: http://hdl.handle.net/10316/8177
DOI: 10.1002/macp.200700015
Rights: openAccess
Appears in Collections:FCTUC Eng.Química - Artigos em Revistas Internacionais

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