Please use this identifier to cite or link to this item: http://hdl.handle.net/10316/17785
DC FieldValueLanguage
dc.contributor.authorPettersson, M.-
dc.contributor.authorMaçoas, E. M. S.-
dc.contributor.authorKhriachtchev, L.-
dc.contributor.authorLundell, J.-
dc.contributor.authorFausto, R.-
dc.contributor.authorRäsänen, M.-
dc.date.accessioned2011-12-02T12:27:30Z-
dc.date.available2011-12-02T12:27:30Z-
dc.date.issued2002-
dc.identifier.urihttp://hdl.handle.net/10316/17785-
dc.description.abstractThe relaxation of the higher-energy cis conformer of formic acid to the lower-energy trans form by a tunneling mechanism has been investigated in low-temperature rare gas matrices. In the temperature range 8–60 K, the tunneling takes place dominantly from the vibrational ground state of the cis form and the temperature dependence of the tunneling rate constant is influenced by the interactions with the environment. The temperature-dependent tunneling rates for HCOOH and DCOOH in solid Ar, Kr, and Xe are measured including data for molecules in different local environments within each host. It was found that the medium and the local environment has a significant influence on the tunnelingpor
dc.language.isoengpor
dc.publisherAmerican Institute of Physicspor
dc.rightsopenAccesspor
dc.titleCis→trans conversion of formic acid by dissipative tunneling in solid rare gases: Influence of environment on the tunneling rate.por
dc.typearticlepor
degois.publication.firstPage9095por
degois.publication.titleJournal of Chemical Physicspor
dc.peerreviewedYespor
dc.identifier.doi10.1063/1.1521429-
degois.publication.volume117por
item.fulltextCom Texto completo-
item.grantfulltextopen-
item.languageiso639-1en-
crisitem.author.deptFaculdade de Ciências e Tecnologia, Universidade de Coimbra-
crisitem.author.parentdeptUniversidade de Coimbra-
crisitem.author.researchunitCoimbra Chemistry Center-
crisitem.author.orcid0000-0002-8264-6854-
Appears in Collections:FCTUC Química - Artigos em Revistas Internacionais
Files in This Item:
File Description SizeFormat
J.Chem.Phys.,117 (2002) 9095.pdf87.73 kBAdobe PDFView/Open
Show simple item record

SCOPUSTM   
Citations

129
checked on Nov 7, 2019

WEB OF SCIENCETM
Citations

129
checked on Nov 7, 2019

Page view(s)

105
checked on Nov 12, 2019

Download(s) 50

237
checked on Nov 12, 2019

Google ScholarTM

Check

Altmetric

Dimensions


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.