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https://hdl.handle.net/10316/13017| Title: | Reactivity of a-Oxophosphonium Ylides: A Contribution to the Mechanistics | Authors: | Melo, Teresa M. Pinho e Gonsalves, António M. d'A. Rocha Carrapato, Sara M. Taborda, Ana M. |
Keywords: | Phosphorus ylides; Tetrasubstituted alkenes | Issue Date: | 1999 | Publisher: | Molecular Diversity Preservation International | Citation: | Molecules. 4:7 (1999) 219-231 | Serial title, monograph or event: | Molecules | Issue: | 4:7 | Abstract: | Ylides 1f and 1g react with chlorine, with bromine and with N-chlorosuccinimide in the presence of a range of nucleophiles. The 2,3-disubstitutedbutenedioates obtained in this way allow us to gather more information about the mechanism involved. Ylide 1c was also studied showing similar reactivity and leading to the highly selective synthesis of 2,3- disubstituted-3-phenylpropenoates | URI: | https://hdl.handle.net/10316/13017 | ISSN: | 1420-3049 | DOI: | 10.3390/40700219 | Rights: | openAccess |
| Appears in Collections: | FCTUC Química - Artigos em Revistas Internacionais |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| Reactivity of a-Oxophosphonium Ylides.pdf | 48.02 kB | Adobe PDF | View/Open |
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