Please use this identifier to cite or link to this item:
https://hdl.handle.net/10316/10288
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Carvalho, Maria de Conceicão Ramos de | - |
dc.contributor.author | Eargle Jr., Dolan H. | - |
dc.date.accessioned | 2009-06-24T09:00:30Z | - |
dc.date.available | 2009-06-24T09:00:30Z | - |
dc.date.issued | 1973-06 | - |
dc.identifier.citation | The Journal of Physical Chemistry. 77:13 (1973) 1716-1718 | en_US |
dc.identifier.uri | https://hdl.handle.net/10316/10288 | - |
dc.description.abstract | The anion radical of tetracyanodithiin (I) is shown to be a divalent sulfur system in which d-orbital participation in conjugation is negligible. The g value (2.0024) indicates that spin-orbit coupling is very small, and a molecular =ode1 shows that direct A-A overlap of the ethylene moieties is probable. Other S-containing cation and anion systems are compared, including 2,5-diphenyldithiin (IV) and tetracyanothiophene (VI). Large cation g value deviations and small anion deviations of S heterocycles are contrasted with hydrocarbons | en_US |
dc.language.iso | eng | en_US |
dc.publisher | American Chemical Society | en_US |
dc.rights | openAccess | eng |
dc.title | Electron paramagnetic resonance study of .pi. system interaction in dithiin derivatives | en_US |
dc.type | article | en_US |
dc.identifier.doi | 10.1021/j100632a025 | - |
item.fulltext | Com Texto completo | - |
item.grantfulltext | open | - |
item.languageiso639-1 | en | - |
item.cerifentitytype | Publications | - |
item.openairetype | article | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
Appears in Collections: | FCTUC Química - Artigos em Revistas Internacionais |
Files in This Item:
File | Description | Size | Format | |
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An Electron Paramagnetic Resonance Study.pdf | 359.35 kB | Adobe PDF | View/Open |
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